1 | MODULE sedsol |
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2 | !!====================================================================== |
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3 | !! *** MODULE sedsol *** |
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4 | !! Sediment : dissolution and reaction in pore water related |
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5 | !! related to organic matter |
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6 | !! Diffusion of solutes in pore water |
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7 | !!===================================================================== |
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8 | !! * Modules used |
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9 | USE sed ! sediment global variable |
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10 | USE sed_oce |
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11 | USE sedini |
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12 | USE seddiff |
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13 | USE seddsr |
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14 | USE sedinorg |
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15 | USE lib_mpp ! distribued memory computing library |
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16 | USE lib_fortran |
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17 | |
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18 | IMPLICIT NONE |
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19 | PRIVATE |
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20 | |
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21 | PUBLIC sed_sol |
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22 | |
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23 | !! * Module variables |
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24 | |
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25 | !! $Id: sedsol.F90 5215 2015-04-15 16:11:56Z nicolasmartin $ |
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26 | CONTAINS |
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27 | |
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28 | SUBROUTINE sed_sol( kt ) |
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29 | !!---------------------------------------------------------------------- |
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30 | !! *** ROUTINE sed_sol *** |
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31 | !! |
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32 | !! ** Purpose : computes pore water diffusion and reactions |
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33 | !! |
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34 | !! ** Methode : Computation of the redox and dissolution reactions |
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35 | !! in the sediment. |
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36 | !! The main redox reactions are solved in sed_dsr whereas |
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37 | !! the secondary reactions are solved in sed_dsr_redoxb. |
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38 | !! Inorganic dissolution is solved in sed_inorg |
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39 | !! A strand spliting approach is being used here (see |
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40 | !! sed_dsr_redoxb for more information). |
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41 | !! Diffusive fluxes are computed in sed_diff |
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42 | !! |
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43 | !! History : |
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44 | !! ! 98-08 (E. Maier-Reimer, Christoph Heinze ) Original code |
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45 | !! ! 04-10 (N. Emprin, M. Gehlen ) f90 |
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46 | !! ! 06-04 (C. Ethe) Re-organization |
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47 | !! ! 19-08 (O. Aumont) Debugging and improvement of the model. |
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48 | !! The original method is replaced by a |
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49 | !! Strand splitting method which deals |
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50 | !! well with stiff reactions. |
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51 | !!---------------------------------------------------------------------- |
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52 | !! Arguments |
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53 | INTEGER, INTENT(in) :: kt |
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54 | ! --- local variables |
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55 | INTEGER :: ji, jk, js, jw, jnt ! dummy looop indices |
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56 | REAL(wp) :: zadsnh4 |
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57 | !! |
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58 | !!---------------------------------------------------------------------- |
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59 | |
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60 | IF( ln_timing ) CALL timing_start('sed_sol') |
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61 | ! |
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62 | IF( kt == nitsed000 ) THEN |
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63 | IF (lwp) THEN |
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64 | WRITE(numsed,*) ' sed_sol : Organic/inorganic degradation related reactions and diffusion' |
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65 | WRITE(numsed,*) ' ' |
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66 | ENDIF |
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67 | ! ! |
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68 | dens_mol_wgt(1:jpsol) = denssol / mol_wgt(1:jpsol) |
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69 | ! |
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70 | ENDIF |
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71 | |
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72 | dtsed2 = dtsed / REAL( nrseddt, wp ) |
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73 | |
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74 | ! 1. Change of geometry |
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75 | ! Increase of dz3d(2) thickness : dz3d(2) = dz3d(2)+dzdep |
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76 | ! Warning : no change for dz(2) |
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77 | !--------------------------------------------------------- |
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78 | dz3d(1:jpoce,2) = dz3d(1:jpoce,2) + dzdep(1:jpoce) |
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79 | |
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80 | ! New values for volw3d(:,2) and vols3d(:,2) |
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81 | ! Warning : no change neither for volw(2) nor vols(2) |
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82 | !------------------------------------------------------ |
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83 | volw3d(1:jpoce,2) = dz3d(1:jpoce,2) * por(2) |
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84 | vols3d(1:jpoce,2) = dz3d(1:jpoce,2) * por1(2) |
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85 | |
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86 | ! 2. Change of previous solid fractions (due to volum changes) for k=2 |
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87 | !--------------------------------------------------------------------- |
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88 | |
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89 | DO js = 1, jpsol |
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90 | DO ji = 1, jpoce |
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91 | solcp(ji,2,js) = solcp(ji,2,js) * dz(2) / dz3d(ji,2) |
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92 | ENDDO |
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93 | END DO |
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94 | |
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95 | ! 3. New solid fractions (including solid rain fractions) for k=2 |
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96 | !------------------------------------------------------------------ |
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97 | DO js = 1, jpsol |
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98 | DO ji = 1, jpoce |
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99 | IF (raintg(ji) .ne. 0) THEN |
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100 | solcp(ji,2,js) = solcp(ji,2,js) + & |
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101 | & ( rainrg(ji,js) / raintg(ji) ) * ( dzdep(ji) / dz3d(ji,2) ) |
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102 | ! rainrm are temporary cancel |
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103 | rainrm(ji,js) = 0. |
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104 | ENDIF |
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105 | END DO |
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106 | ENDDO |
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107 | |
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108 | ! 4. Adjustment of bottom water concen.(pwcp(1)): |
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109 | ! We impose that pwcp(2) is constant. Including dzdep in dz3d(:,2) we assume |
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110 | ! that dzdep has got a porosity of por(2). So pore water volum of jk=2 increase. |
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111 | ! To keep pwcp(2) cste we must compensate this "increase" by a slight adjusment |
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112 | ! of bottom water concentration. |
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113 | ! This adjustment is compensate at the end of routine |
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114 | !------------------------------------------------------------- |
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115 | DO jw = 1, jpwat |
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116 | DO ji = 1, jpoce |
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117 | pwcp(ji,1,jw) = pwcp(ji,1,jw) - & |
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118 | & pwcp(ji,2,jw) * dzdep(ji) * por(2) / ( dzkbot(ji) + rtrn ) |
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119 | END DO |
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120 | ENDDO |
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121 | |
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122 | zadsnh4 = 1.0 / ( 1.0 + adsnh4 ) |
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123 | |
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124 | ! -------------------------------------------------- |
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125 | ! Computation of the diffusivities |
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126 | ! -------------------------------------------------- |
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127 | |
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128 | DO js = 1, jpwat |
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129 | DO jk = 1, jpksed |
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130 | DO ji = 1, jpoce |
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131 | diff(ji,jk,js) = ( diff1(js) + diff2(js) * temp(ji) ) / ( 1.0 - 2.0 * log( por(jk) ) ) |
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132 | END DO |
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133 | END DO |
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134 | END DO |
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135 | |
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136 | ! Impact of bioirrigation and adsorption on diffusion |
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137 | ! --------------------------------------------------- |
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138 | |
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139 | diff(:,:,jwnh4) = diff(:,:,jwnh4) * ( 1.0 + irrig(:,:) ) * zadsnh4 |
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140 | diff(:,:,jwsil) = diff(:,:,jwsil) * ( 1.0 + irrig(:,:) ) |
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141 | diff(:,:,jwoxy) = diff(:,:,jwoxy) * ( 1.0 + irrig(:,:) ) |
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142 | diff(:,:,jwdic) = diff(:,:,jwdic) * ( 1.0 + irrig(:,:) ) |
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143 | diff(:,:,jwno3) = diff(:,:,jwno3) * ( 1.0 + irrig(:,:) ) |
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144 | diff(:,:,jwpo4) = diff(:,:,jwpo4) * ( 1.0 + irrig(:,:) ) |
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145 | diff(:,:,jwalk) = diff(:,:,jwalk) * ( 1.0 + irrig(:,:) ) |
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146 | diff(:,:,jwh2s) = diff(:,:,jwh2s) * ( 1.0 + irrig(:,:) ) |
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147 | diff(:,:,jwso4) = diff(:,:,jwso4) * ( 1.0 + irrig(:,:) ) |
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148 | diff(:,:,jwfe2) = diff(:,:,jwfe2) * ( 1.0 + 0.2 * irrig(:,:) ) |
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149 | |
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150 | DO jnt = 1, nrseddt |
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151 | CALL sed_diff( kt, jnt ) ! 1st pass in diffusion to get values at t+1/2 |
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152 | CALL sed_dsr ( kt, jnt ) ! Redox reactions |
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153 | CALL sed_inorg( kt, jnt ) ! Inorganic reactions (dissolution) |
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154 | CALL sed_diff ( kt, jnt ) ! 2nd pass in diffusion to get values at t+1 |
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155 | END DO |
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156 | |
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157 | !---------------------------------- |
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158 | ! Back to initial geometry |
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159 | !----------------------------- |
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160 | |
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161 | !--------------------------------------------------------------------- |
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162 | ! 1/ Compensation for ajustement of the bottom water concentrations |
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163 | ! (see note n� 1 about *por(2)) |
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164 | !-------------------------------------------------------------------- |
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165 | DO jw = 1, jpwat |
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166 | DO ji = 1, jpoce |
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167 | pwcp(ji,1,jw) = pwcp(ji,1,jw) + & |
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168 | & pwcp(ji,2,jw) * dzdep(ji) * por(2) / dzkbot(ji) |
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169 | END DO |
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170 | ENDDO |
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171 | |
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172 | !----------------------------------------------------------------------- |
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173 | ! 2/ Det of new rainrg taking account of the new weight fraction |
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174 | ! obtained |
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175 | ! in dz3d(2) after diffusion/reaction (react/diffu are also in |
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176 | ! dzdep!) |
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177 | ! This new rain (rgntg rm) will be used in advection/burial routine |
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178 | !------------------------------------------------------------------------ |
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179 | DO js = 1, jpsol |
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180 | DO ji = 1, jpoce |
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181 | rainrg(ji,js) = raintg(ji) * solcp(ji,2,js) |
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182 | rainrm(ji,js) = rainrg(ji,js) / mol_wgt(js) |
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183 | END DO |
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184 | ENDDO |
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185 | |
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186 | ! New raintg |
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187 | raintg(:) = 0. |
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188 | DO js = 1, jpsol |
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189 | DO ji = 1, jpoce |
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190 | raintg(ji) = raintg(ji) + rainrg(ji,js) |
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191 | END DO |
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192 | ENDDO |
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193 | |
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194 | !-------------------------------- |
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195 | ! 3/ back to initial geometry |
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196 | !-------------------------------- |
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197 | DO ji = 1, jpoce |
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198 | dz3d (ji,2) = dz(2) |
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199 | volw3d(ji,2) = dz3d(ji,2) * por(2) |
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200 | vols3d(ji,2) = dz3d(ji,2) * por1(2) |
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201 | ENDDO |
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202 | |
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203 | IF( ln_timing ) CALL timing_stop('sed_sol') |
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204 | ! |
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205 | END SUBROUTINE sed_sol |
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206 | |
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207 | END MODULE sedsol |
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