| [3443] | 1 | MODULE p4zfechem |
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| 2 | !!====================================================================== |
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| 3 | !! *** MODULE p4zfechem *** |
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| 4 | !! TOP : PISCES Compute iron chemistry and scavenging |
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| 5 | !!====================================================================== |
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| [3461] | 6 | !! History : 3.5 ! 2012-07 (O. Aumont, A. Tagliabue, C. Ethe) Original code |
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| [6453] | 7 | !! 3.6 ! 2015-05 (O. Aumont) PISCES quota |
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| [3443] | 8 | !!---------------------------------------------------------------------- |
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| [6453] | 9 | #if defined key_pisces || defined key_pisces_quota |
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| [3443] | 10 | !!---------------------------------------------------------------------- |
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| 11 | !! 'key_top' and TOP models |
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| [6453] | 12 | !! 'key_pisces*' PISCES bio-model |
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| [3443] | 13 | !!---------------------------------------------------------------------- |
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| 14 | !! p4z_fechem : Compute remineralization/scavenging of iron |
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| 15 | !! p4z_fechem_init : Initialisation of parameters for remineralisation |
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| 16 | !! p4z_fechem_alloc : Allocate remineralisation variables |
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| 17 | !!---------------------------------------------------------------------- |
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| 18 | USE oce_trc ! shared variables between ocean and passive tracers |
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| 19 | USE trc ! passive tracers common variables |
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| 20 | USE sms_pisces ! PISCES Source Minus Sink variables |
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| 21 | USE p4zopt ! optical model |
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| 22 | USE p4zche ! chemical model |
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| 23 | USE p4zsbc ! Boundary conditions from sediments |
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| 24 | USE prtctl_trc ! print control for debugging |
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| 25 | USE iom ! I/O manager |
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| 26 | |
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| 27 | IMPLICIT NONE |
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| 28 | PRIVATE |
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| 29 | |
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| 30 | PUBLIC p4z_fechem ! called in p4zbio.F90 |
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| 31 | PUBLIC p4z_fechem_init ! called in trcsms_pisces.F90 |
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| 32 | |
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| 33 | !! * Shared module variables |
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| [4147] | 34 | LOGICAL :: ln_fechem !: boolean for complex iron chemistry following Tagliabue and voelker |
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| 35 | LOGICAL :: ln_ligvar !: boolean for variable ligand concentration following Tagliabue and voelker |
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| [6453] | 36 | LOGICAL :: ln_fecolloid !: boolean for variable colloidal fraction |
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| [4147] | 37 | REAL(wp), PUBLIC :: xlam1 !: scavenging rate of Iron |
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| 38 | REAL(wp), PUBLIC :: xlamdust !: scavenging rate of Iron by dust |
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| 39 | REAL(wp), PUBLIC :: ligand !: ligand concentration in the ocean |
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| [6453] | 40 | REAL(wp), PUBLIC :: kfep !: rate constant for nanoparticle formation |
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| [3443] | 41 | |
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| [3446] | 42 | REAL(wp) :: kl1, kl2, kb1, kb2, ks, kpr, spd, con, kth |
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| [3443] | 43 | |
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| 44 | !!* Substitution |
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| 45 | # include "top_substitute.h90" |
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| 46 | !!---------------------------------------------------------------------- |
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| 47 | !! NEMO/TOP 3.3 , NEMO Consortium (2010) |
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| 48 | !! $Id: p4zrem.F90 3160 2011-11-20 14:27:18Z cetlod $ |
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| 49 | !! Software governed by the CeCILL licence (NEMOGCM/NEMO_CeCILL.txt) |
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| 50 | !!---------------------------------------------------------------------- |
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| 51 | CONTAINS |
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| 52 | |
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| [6453] | 53 | SUBROUTINE p4z_fechem( kt, jnt ) |
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| [3443] | 54 | !!--------------------------------------------------------------------- |
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| 55 | !! *** ROUTINE p4z_fechem *** |
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| 56 | !! |
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| 57 | !! ** Purpose : Compute remineralization/scavenging of iron |
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| 58 | !! |
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| 59 | !! ** Method : 2 different chemistry models are available for iron |
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| 60 | !! (1) The simple chemistry model of Aumont and Bopp (2006) |
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| 61 | !! based on one ligand and one inorganic form |
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| 62 | !! (2) The complex chemistry model of Tagliabue and |
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| 63 | !! Voelker (2009) based on 2 ligands, 2 inorganic forms |
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| 64 | !! and one particulate form (ln_fechem) |
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| 65 | !!--------------------------------------------------------------------- |
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| 66 | ! |
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| [6453] | 67 | INTEGER, INTENT(in) :: kt, jnt ! ocean time step |
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| [3443] | 68 | ! |
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| [6453] | 69 | INTEGER :: ji, jj, jk, jic, jn |
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| [3446] | 70 | REAL(wp) :: zdep, zlam1a, zlam1b, zlamfac |
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| [7617] | 71 | REAL(wp) :: zkeq, zfeequi, zfesatur, zfecoll, zfecollc, fe3sol, fe3sol1 |
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| [3446] | 72 | REAL(wp) :: zdenom1, zscave, zaggdfea, zaggdfeb, zcoag |
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| [3443] | 73 | REAL(wp) :: ztrc, zdust |
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| 74 | #if ! defined key_kriest |
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| [6841] | 75 | REAL(wp) :: zdenom2 |
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| [3443] | 76 | #endif |
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| [6453] | 77 | REAL(wp), POINTER, DIMENSION(:,:,:) :: zTL1, zFe3, ztotlig, precip |
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| [3443] | 78 | REAL(wp), POINTER, DIMENSION(:,:,:) :: zFeL1, zFeL2, zTL2, zFe2, zFeP |
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| [6453] | 79 | REAL(wp), POINTER, DIMENSION(:,: ) :: zstrn, zstrn2 |
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| [7617] | 80 | REAL(wp), POINTER, DIMENSION(:,:,:) :: zcoll3d, zscav3d |
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| [6453] | 81 | REAL(wp) :: zzFeL1, zzFeL2, zzFe2, zzFeP, zzFe3, zzstrn2 |
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| [6841] | 82 | REAL(wp) :: zrum, zcodel, zargu, zlight |
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| [3446] | 83 | REAL(wp) :: zkox, zkph1, zkph2, zph, zionic, ztligand |
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| [3443] | 84 | REAL(wp) :: za, zb, zc, zkappa1, zkappa2, za0, za1, za2 |
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| 85 | REAL(wp) :: zxs, zfunc, zp, zq, zd, zr, zphi, zfff, zp3, zq2 |
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| [6453] | 86 | REAL(wp) :: ztfe, zoxy, zhplus |
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| [7617] | 87 | REAL(wp) :: zstep, zrfact2 |
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| [6453] | 88 | #if defined key_ligand |
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| 89 | REAL(wp) :: zaggliga, zaggligb |
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| 90 | REAL(wp) :: dissol, zligco |
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| [7617] | 91 | REAL(wp), POINTER, DIMENSION(:,:,:) :: zlcoll3d |
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| [6453] | 92 | #endif |
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| [3443] | 93 | CHARACTER (len=25) :: charout |
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| 94 | !!--------------------------------------------------------------------- |
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| 95 | ! |
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| 96 | IF( nn_timing == 1 ) CALL timing_start('p4z_fechem') |
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| 97 | ! |
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| 98 | ! Allocate temporary workspace |
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| [6453] | 99 | CALL wrk_alloc( jpi, jpj, jpk, zFe3, zFeL1, zTL1, ztotlig, precip ) |
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| [7617] | 100 | CALL wrk_alloc( jpi, jpj, jpk, zcoll3d, zscav3d ) |
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| 101 | #if defined key_ligand |
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| 102 | CALL wrk_alloc( jpi, jpj, jpk, zlcoll3d ) |
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| 103 | #endif |
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| [3531] | 104 | zFe3 (:,:,:) = 0. |
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| 105 | zFeL1(:,:,:) = 0. |
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| 106 | zTL1 (:,:,:) = 0. |
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| 107 | IF( ln_fechem ) THEN |
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| [6453] | 108 | CALL wrk_alloc( jpi, jpj, zstrn, zstrn2 ) |
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| [3531] | 109 | CALL wrk_alloc( jpi, jpj, jpk, zFe2, zFeL2, zTL2, zFeP ) |
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| 110 | zFe2 (:,:,:) = 0. |
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| 111 | zFeL2(:,:,:) = 0. |
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| 112 | zTL2 (:,:,:) = 0. |
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| 113 | zFeP (:,:,:) = 0. |
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| 114 | ENDIF |
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| [3461] | 115 | |
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| [3443] | 116 | ! Total ligand concentration : Ligands can be chosen to be constant or variable |
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| 117 | ! Parameterization from Tagliabue and Voelker (2011) |
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| 118 | ! ------------------------------------------------- |
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| 119 | IF( ln_ligvar ) THEN |
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| [5385] | 120 | ztotlig(:,:,:) = 0.09 * trb(:,:,:,jpdoc) * 1E6 + ligand * 1E9 |
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| [3446] | 121 | ztotlig(:,:,:) = MIN( ztotlig(:,:,:), 10. ) |
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| [3443] | 122 | ELSE |
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| [6453] | 123 | #if defined key_ligand |
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| 124 | ztotlig(:,:,:) = trb(:,:,:,jplgw) * 1E9 |
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| 125 | #else |
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| [3443] | 126 | ztotlig(:,:,:) = ligand * 1E9 |
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| [6453] | 127 | #endif |
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| [3443] | 128 | ENDIF |
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| 129 | |
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| 130 | IF( ln_fechem ) THEN |
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| [6453] | 131 | |
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| 132 | ! compute the day length depending on latitude and the day |
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| 133 | zrum = REAL( nday_year - 80, wp ) / REAL( nyear_len(1), wp ) |
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| 134 | zcodel = ASIN( SIN( zrum * rpi * 2._wp ) * SIN( rad * 23.5_wp ) ) |
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| 135 | |
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| 136 | ! day length in hours |
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| 137 | zstrn(:,:) = 0. |
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| 138 | DO jj = 1, jpj |
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| 139 | DO ji = 1, jpi |
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| 140 | zargu = TAN( zcodel ) * TAN( gphit(ji,jj) * rad ) |
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| 141 | zargu = MAX( -1., MIN( 1., zargu ) ) |
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| 142 | zstrn(ji,jj) = MAX( 0.0, 24. - 2. * ACOS( zargu ) / rad / 15. ) |
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| 143 | END DO |
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| 144 | END DO |
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| 145 | |
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| 146 | ! Maximum light intensity |
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| 147 | zstrn2(:,:) = zstrn(:,:) / 24. |
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| 148 | WHERE( zstrn(:,:) < 1.e0 ) zstrn(:,:) = 24. |
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| 149 | zstrn(:,:) = 24. / zstrn(:,:) |
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| 150 | |
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| [3443] | 151 | ! ------------------------------------------------------------ |
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| 152 | ! NEW FE CHEMISTRY ROUTINE from Tagliabue and Volker (2009) |
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| 153 | ! This model is based on two ligands, Fe2+, Fe3+ and Fep |
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| 154 | ! Chemistry is supposed to be fast enough to be at equilibrium |
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| 155 | ! ------------------------------------------------------------ |
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| [6453] | 156 | DO jn = 1, 2 |
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| [3531] | 157 | !CDIR NOVERRCHK |
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| [3443] | 158 | DO jk = 1, jpkm1 |
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| [3531] | 159 | !CDIR NOVERRCHK |
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| [3443] | 160 | DO jj = 1, jpj |
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| [3531] | 161 | !CDIR NOVERRCHK |
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| [3443] | 162 | DO ji = 1, jpi |
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| [6453] | 163 | zlight = etot(ji,jj,jk) * zstrn(ji,jj) * float(2-jn) |
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| 164 | zzstrn2 = zstrn2(ji,jj) * float(2-jn) + (1. - zstrn2(ji,jj) ) * float(jn-1) |
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| [3461] | 165 | ! Calculate ligand concentrations : assume 2/3rd of excess goes to |
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| 166 | ! strong ligands (L1) and 1/3rd to weak ligands (L2) |
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| [3446] | 167 | ztligand = ztotlig(ji,jj,jk) - ligand * 1E9 |
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| [3461] | 168 | zTL1(ji,jj,jk) = 0.000001 + 0.67 * ztligand |
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| 169 | zTL2(ji,jj,jk) = ligand * 1E9 - 0.000001 + 0.33 * ztligand |
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| [3443] | 170 | ! ionic strength from Millero et al. 1987 |
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| 171 | zph = -LOG10( MAX( hi(ji,jj,jk), rtrn) ) |
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| [6966] | 172 | zoxy = trb(ji,jj,jk,jpoxy) |
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| [3461] | 173 | ! Fe2+ oxydation rate from Santana-Casiano et al. (2005) |
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| [6966] | 174 | zkox = 35.407 - 6.7109 * zph + 0.5342 * zph * zph - 5362.6 / ( tempis(ji,jj,jk) + 273.15 ) & |
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| 175 | & - 0.04406 * SQRT( salinprac(ji,jj,jk) ) - 0.002847 * salinprac(ji,jj,jk) |
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| [3461] | 176 | zkox = ( 10.** zkox ) * spd |
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| 177 | zkox = zkox * MAX( 1.e-6, zoxy) / ( chemo2(ji,jj,jk) + rtrn ) |
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| [3443] | 178 | ! PHOTOREDUCTION of complexed iron : Tagliabue and Arrigo (2006) |
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| [6841] | 179 | zkph2 = MAX( 0., 15. * zlight / ( zlight + 2. ) ) * (1. - fr_i(ji,jj)) |
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| [3461] | 180 | zkph1 = zkph2 / 5. |
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| [3443] | 181 | ! pass the dfe concentration from PISCES |
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| [5385] | 182 | ztfe = trb(ji,jj,jk,jpfer) * 1e9 |
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| [3443] | 183 | ! ---------------------------------------------------------- |
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| 184 | ! ANALYTICAL SOLUTION OF ROOTS OF THE FE3+ EQUATION |
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| 185 | ! As shown in Tagliabue and Voelker (2009), Fe3+ is the root of a 3rd order polynom. |
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| 186 | ! ---------------------------------------------------------- |
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| 187 | ! calculate some parameters |
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| 188 | za = 1 + ks / kpr |
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| [3446] | 189 | zb = 1 + ( zkph1 + kth ) / ( zkox + rtrn ) |
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| [3443] | 190 | zc = 1 + zkph2 / ( zkox + rtrn ) |
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| [3446] | 191 | zkappa1 = ( kb1 + zkph1 + kth ) / kl1 |
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| 192 | zkappa2 = ( kb2 + zkph2 ) / kl2 |
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| [3443] | 193 | za2 = zTL1(ji,jj,jk) * zb / za + zTL2(ji,jj,jk) * zc / za + zkappa1 + zkappa2 - ztfe / za |
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| 194 | za1 = zkappa2 * zTL1(ji,jj,jk) * zb / za + zkappa1 * zTL2(ji,jj,jk) * zc / za & |
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| 195 | & + zkappa1 * zkappa2 - ( zkappa1 + zkappa2 ) * ztfe / za |
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| 196 | za0 = -zkappa1 * zkappa2 * ztfe / za |
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| 197 | zp = za1 - za2 * za2 / 3. |
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| 198 | zq = za2 * za2 * za2 * 2. / 27. - za2 * za1 / 3. + za0 |
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| 199 | zp3 = zp / 3. |
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| 200 | zq2 = zq / 2. |
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| 201 | zd = zp3 * zp3 * zp3 + zq2 * zq2 |
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| 202 | zr = zq / ABS( zq ) * SQRT( ABS( zp ) / 3. ) |
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| 203 | ! compute the roots |
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| 204 | IF( zp > 0.) THEN |
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| [3450] | 205 | ! zphi = ASINH( zq / ( 2. * zr * zr * zr ) ) |
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| 206 | zphi = zq / ( 2. * zr * zr * zr ) |
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| [3461] | 207 | zphi = LOG( zphi + SQRT( zphi * zphi + 1 ) ) ! asinh(x) = log(x + sqrt(x^2+1)) |
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| [3443] | 208 | zxs = -2. * zr * SINH( zphi / 3. ) - za1 / 3. |
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| 209 | ELSE |
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| 210 | IF( zd > 0. ) THEN |
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| 211 | zfff = MAX( 1., zq / ( 2. * zr * zr * zr ) ) |
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| [3461] | 212 | ! zphi = ACOSH( zfff ) |
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| 213 | zphi = LOG( zfff + SQRT( zfff * zfff - 1 ) ) ! acosh(x) = log(x + sqrt(x^2-1)) |
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| [3443] | 214 | zxs = -2. * zr * COSH( zphi / 3. ) - za1 / 3. |
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| 215 | ELSE |
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| [3461] | 216 | zfff = MIN( 1., zq / ( 2. * zr * zr * zr ) ) |
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| [3456] | 217 | zphi = ACOS( zfff ) |
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| [3443] | 218 | DO jic = 1, 3 |
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| 219 | zfunc = -2 * zr * COS( zphi / 3. + 2. * FLOAT( jic - 1 ) * rpi / 3. ) - za2 / 3. |
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| 220 | IF( zfunc > 0. .AND. zfunc <= ztfe) zxs = zfunc |
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| 221 | END DO |
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| 222 | ENDIF |
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| 223 | ENDIF |
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| 224 | ! solve for the other Fe species |
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| [6453] | 225 | zzFe3 = MAX( 0., zxs ) |
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| 226 | zzFep = MAX( 0., ( ks * zzFe3 / kpr ) ) |
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| [3448] | 227 | zkappa2 = ( kb2 + zkph2 ) / kl2 |
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| [6453] | 228 | zzFeL2 = MAX( 0., ( zzFe3 * zTL2(ji,jj,jk) ) / ( zkappa2 + zzFe3 ) ) |
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| 229 | zzFeL1 = MAX( 0., ( ztfe / zb - za / zb * zzFe3 - zc / zb * zzFeL2 ) ) |
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| 230 | zzFe2 = MAX( 0., ( ( zkph1 * zzFeL1 + zkph2 * zzFeL2 ) / zkox ) ) |
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| 231 | zFe3(ji,jj,jk) = zFe3(ji,jj,jk) + zzFe3 * zzstrn2 |
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| 232 | zFe2(ji,jj,jk) = zFe2(ji,jj,jk) + zzFe2 * zzstrn2 |
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| 233 | zFeL2(ji,jj,jk) = zFeL2(ji,jj,jk) + zzFeL2 * zzstrn2 |
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| 234 | zFeL1(ji,jj,jk) = zFeL1(ji,jj,jk) + zzFeL1 * zzstrn2 |
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| 235 | zFeP(ji,jj,jk) = zFeP(ji,jj,jk) + zzFeP * zzstrn2 |
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| [3443] | 236 | END DO |
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| 237 | END DO |
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| 238 | END DO |
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| [6453] | 239 | END DO |
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| [3443] | 240 | ELSE |
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| 241 | ! ------------------------------------------------------------ |
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| 242 | ! OLD FE CHEMISTRY ROUTINE from Aumont and Bopp (2006) |
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| 243 | ! This model is based on one ligand and Fe' |
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| 244 | ! Chemistry is supposed to be fast enough to be at equilibrium |
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| 245 | ! ------------------------------------------------------------ |
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| [3531] | 246 | !CDIR NOVERRCHK |
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| [3443] | 247 | DO jk = 1, jpkm1 |
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| [3531] | 248 | !CDIR NOVERRCHK |
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| [3443] | 249 | DO jj = 1, jpj |
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| [3531] | 250 | !CDIR NOVERRCHK |
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| [3443] | 251 | DO ji = 1, jpi |
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| 252 | zTL1(ji,jj,jk) = ztotlig(ji,jj,jk) |
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| 253 | zkeq = fekeq(ji,jj,jk) |
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| 254 | zfesatur = zTL1(ji,jj,jk) * 1E-9 |
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| [5385] | 255 | ztfe = trb(ji,jj,jk,jpfer) |
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| [3443] | 256 | ! Fe' is the root of a 2nd order polynom |
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| [3448] | 257 | zFe3 (ji,jj,jk) = ( -( 1. + zfesatur * zkeq - zkeq * ztfe ) & |
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| [3443] | 258 | & + SQRT( ( 1. + zfesatur * zkeq - zkeq * ztfe )**2 & |
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| 259 | & + 4. * ztfe * zkeq) ) / ( 2. * zkeq ) |
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| [3448] | 260 | zFe3 (ji,jj,jk) = zFe3(ji,jj,jk) * 1E9 |
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| [5385] | 261 | zFeL1(ji,jj,jk) = MAX( 0., trb(ji,jj,jk,jpfer) * 1E9 - zFe3(ji,jj,jk) ) |
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| [3443] | 262 | END DO |
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| 263 | END DO |
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| 264 | END DO |
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| 265 | ! |
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| 266 | ENDIF |
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| 267 | |
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| [3531] | 268 | zdust = 0. ! if no dust available |
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| [3443] | 269 | !CDIR NOVERRCHK |
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| 270 | DO jk = 1, jpkm1 |
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| 271 | !CDIR NOVERRCHK |
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| 272 | DO jj = 1, jpj |
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| 273 | !CDIR NOVERRCHK |
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| 274 | DO ji = 1, jpi |
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| 275 | zstep = xstep |
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| 276 | # if defined key_degrad |
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| 277 | zstep = zstep * facvol(ji,jj,jk) |
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| 278 | # endif |
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| 279 | ! Scavenging rate of iron. This scavenging rate depends on the load of particles of sea water. |
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| 280 | ! This parameterization assumes a simple second order kinetics (k[Particles][Fe]). |
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| 281 | ! Scavenging onto dust is also included as evidenced from the DUNE experiments. |
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| 282 | ! -------------------------------------------------------------------------------------- |
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| [3446] | 283 | IF( ln_fechem ) THEN |
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| [4521] | 284 | zfeequi = ( zFe3(ji,jj,jk) + zFe2(ji,jj,jk) + zFeP(ji,jj,jk) ) * 1E-9 |
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| [3446] | 285 | zfecoll = ( 0.3 * zFeL1(ji,jj,jk) + 0.5 * zFeL2(ji,jj,jk) ) * 1E-9 |
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| 286 | ELSE |
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| [7180] | 287 | zfeequi = zFe3(ji,jj,jk) * 1E-9 |
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| [6453] | 288 | IF (ln_fecolloid) THEN |
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| 289 | zhplus = max( rtrn, hi(ji,jj,jk) ) |
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| [7180] | 290 | fe3sol = fesol(ji,jj,jk,1) * ( zhplus**3 + fesol(ji,jj,jk,2) * zhplus**2 & |
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| [6453] | 291 | & + fesol(ji,jj,jk,3) * zhplus + fesol(ji,jj,jk,4) & |
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| 292 | & + fesol(ji,jj,jk,5) / zhplus ) |
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| 293 | zfecoll = max( ( 0.1 * zFeL1(ji,jj,jk) * 1E-9 ), ( zFeL1(ji,jj,jk) * 1E-9 -fe3sol ) ) |
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| [7180] | 294 | #if defined key_ligand |
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| 295 | zligco = max( ( 0.1 * trn(ji,jj,jk,jplgw) ), ( trn(ji,jj,jk,jplgw) - fe3sol ) ) |
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| 296 | #endif |
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| [6453] | 297 | ELSE |
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| 298 | zfecoll = 0.5 * zFeL1(ji,jj,jk) * 1E-9 |
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| [7180] | 299 | #if defined key_ligand |
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| 300 | zligco = 0.5 * trn(ji,jj,jk,jplgw) |
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| 301 | #endif |
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| [6453] | 302 | fe3sol = 0. |
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| 303 | ENDIF |
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| [3446] | 304 | ENDIF |
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| [3443] | 305 | #if defined key_kriest |
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| [5385] | 306 | ztrc = ( trb(ji,jj,jk,jppoc) + trb(ji,jj,jk,jpcal) + trb(ji,jj,jk,jpgsi) ) * 1.e6 |
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| [3443] | 307 | #else |
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| [5385] | 308 | ztrc = ( trb(ji,jj,jk,jppoc) + trb(ji,jj,jk,jpgoc) + trb(ji,jj,jk,jpcal) + trb(ji,jj,jk,jpgsi) ) * 1.e6 |
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| [3443] | 309 | #endif |
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| [4800] | 310 | IF( ln_dust ) zdust = dust(ji,jj) / ( wdust / rday ) * tmask(ji,jj,jk) ! dust in kg/m2/s |
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| [3443] | 311 | zlam1b = 3.e-5 + xlamdust * zdust + xlam1 * ztrc |
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| 312 | zscave = zfeequi * zlam1b * zstep |
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| 313 | |
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| 314 | ! Compute the different ratios for scavenging of iron |
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| 315 | ! to later allocate scavenged iron to the different organic pools |
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| 316 | ! --------------------------------------------------------- |
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| [5385] | 317 | zdenom1 = xlam1 * trb(ji,jj,jk,jppoc) / zlam1b |
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| [3780] | 318 | #if ! defined key_kriest |
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| [5385] | 319 | zdenom2 = xlam1 * trb(ji,jj,jk,jpgoc) / zlam1b |
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| [3443] | 320 | #endif |
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| 321 | |
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| 322 | ! Increased scavenging for very high iron concentrations found near the coasts |
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| 323 | ! due to increased lithogenic particles and let say it is unknown processes (precipitation, ...) |
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| 324 | ! ----------------------------------------------------------- |
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| [3475] | 325 | zlamfac = MAX( 0.e0, ( gphit(ji,jj) + 55.) / 30. ) |
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| 326 | zlamfac = MIN( 1. , zlamfac ) |
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| 327 | zdep = MIN( 1., 1000. / fsdept(ji,jj,jk) ) |
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| [5385] | 328 | zlam1b = xlam1 * MAX( 0.e0, ( trb(ji,jj,jk,jpfer) * 1.e9 - ztotlig(ji,jj,jk) ) ) |
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| 329 | zcoag = zfeequi * zlam1b * zstep + 1E-4 * ( 1. - zlamfac ) * zdep * zstep * trb(ji,jj,jk,jpfer) |
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| [3443] | 330 | |
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| 331 | ! Compute the coagulation of colloidal iron. This parameterization |
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| 332 | ! could be thought as an equivalent of colloidal pumping. |
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| 333 | ! It requires certainly some more work as it is very poorly constrained. |
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| 334 | ! ---------------------------------------------------------------- |
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| [7617] | 335 | zfecollc = trb(ji,jj,jk,jpdoc) / ( 40.E-6 + trb(ji,jj,jk,jpdoc) ) * zfecoll |
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| [5385] | 336 | zlam1a = ( 0.369 * 0.3 * trb(ji,jj,jk,jpdoc) + 102.4 * trb(ji,jj,jk,jppoc) ) * xdiss(ji,jj,jk) & |
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| [7180] | 337 | & + ( 114. * 0.3 * trb(ji,jj,jk,jpdoc) ) |
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| [7617] | 338 | zaggdfea = zlam1a * zstep * zfecollc |
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| [6453] | 339 | ! |
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| [3443] | 340 | #if defined key_kriest |
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| [3446] | 341 | zaggdfeb = 0. |
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| [3443] | 342 | #else |
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| [5385] | 343 | zlam1b = 3.53E3 * trb(ji,jj,jk,jpgoc) * xdiss(ji,jj,jk) |
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| [7617] | 344 | zaggdfeb = zlam1b * zstep * zfecollc |
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| [7180] | 345 | #endif |
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| [6453] | 346 | ! precipitation of Fe3+, creation of nanoparticles |
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| 347 | precip(ji,jj,jk) = max( 0., (zfeequi - fe3sol) ) * kfep * zstep |
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| 348 | ! |
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| 349 | tra(ji,jj,jk,jpfer) = tra(ji,jj,jk,jpfer) - zscave - zaggdfea - zaggdfeb & |
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| 350 | & - zcoag - precip(ji,jj,jk) |
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| [3446] | 351 | tra(ji,jj,jk,jpsfe) = tra(ji,jj,jk,jpsfe) + zscave * zdenom1 + zaggdfea |
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| [7180] | 352 | #if ! defined key_kriest |
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| [3446] | 353 | tra(ji,jj,jk,jpbfe) = tra(ji,jj,jk,jpbfe) + zscave * zdenom2 + zaggdfeb |
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| [3443] | 354 | #endif |
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| [7617] | 355 | zscav3d(ji,jj,jk) = zscave |
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| 356 | zcoll3d(ji,jj,jk) = zaggdfea + zaggdfeb |
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| [6453] | 357 | #if defined key_ligand |
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| [7180] | 358 | zaggliga = zlam1a * zstep * zligco |
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| 359 | # if defined key_kriest |
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| 360 | zaggligb = 0. |
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| 361 | # else |
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| 362 | zaggligb = zlam1b * zstep * zligco |
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| 363 | # endif |
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| [6453] | 364 | tra(ji,jj,jk,jpfep) = tra(ji,jj,jk,jpfep) + precip(ji,jj,jk) |
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| 365 | tra(ji,jj,jk,jplgw) = tra(ji,jj,jk,jplgw) - zaggliga - zaggligb |
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| [7617] | 366 | zlcoll3d(ji,jj,jk) = zaggliga + zaggligb |
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| [6453] | 367 | #endif |
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| [3443] | 368 | END DO |
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| 369 | END DO |
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| 370 | END DO |
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| 371 | ! |
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| [3446] | 372 | ! Define the bioavailable fraction of iron |
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| 373 | ! ---------------------------------------- |
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| 374 | IF( ln_fechem ) THEN |
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| [5385] | 375 | biron(:,:,:) = MAX( 0., trb(:,:,:,jpfer) - zFeP(:,:,:) * 1E-9 ) |
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| [3446] | 376 | ELSE |
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| [5385] | 377 | biron(:,:,:) = trb(:,:,:,jpfer) |
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| [3446] | 378 | ENDIF |
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| [3443] | 379 | |
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| [6453] | 380 | #if defined key_ligand |
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| 381 | IF (.NOT. ln_fechem) THEN |
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| 382 | plig(:,:,:) = MAX( 0., ( ( zFeL1(:,:,:) * 1E-9 ) / ( trn(:,:,:,jpfer) +rtrn ) ) ) |
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| 383 | plig(:,:,:) = max(0. , plig(:,:,:) ) |
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| 384 | ENDIF |
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| 385 | #endif |
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| 386 | |
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| [3443] | 387 | ! Output of some diagnostics variables |
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| 388 | ! --------------------------------- |
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| [6453] | 389 | IF( ln_diatrc .AND. lk_iomput ) THEN |
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| 390 | IF( jnt == nrdttrc ) THEN |
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| [7617] | 391 | zrfact2 = 1.e3 * rfact2r ! conversion from mol/L/timestep into mol/m3/s |
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| [6453] | 392 | CALL iom_put("Fe3" , zFe3 (:,:,:) * tmask(:,:,:) ) ! Fe3+ |
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| 393 | CALL iom_put("FeL1" , zFeL1 (:,:,:) * tmask(:,:,:) ) ! FeL1 |
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| 394 | CALL iom_put("TL1" , zTL1 (:,:,:) * tmask(:,:,:) ) ! TL1 |
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| 395 | CALL iom_put("Totlig" , ztotlig(:,:,:) * tmask(:,:,:) ) ! TL |
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| [7617] | 396 | CALL iom_put("Biron" , biron (:,:,:) * 1e9 * tmask(:,:,:) ) ! biron |
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| 397 | CALL iom_put("FESCAV" , zscav3d(:,:,:) * 1e9 * tmask(:,:,:) * zrfact2 ) |
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| 398 | CALL iom_put("FECOLL" , zcoll3d(:,:,:) * 1e9 * tmask(:,:,:) * zrfact2 ) |
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| 399 | #if defined key_ligand |
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| 400 | CALL iom_put("LGWCOLL", zlcoll3d(:,:,:) * 1e9 * tmask(:,:,:) * zrfact2 ) |
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| 401 | #endif |
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| [6453] | 402 | IF( ln_fechem ) THEN |
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| 403 | CALL iom_put("Fe2" , zFe2 (:,:,:) * tmask(:,:,:) ) ! Fe2+ |
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| 404 | CALL iom_put("FeL2", zFeL2 (:,:,:) * tmask(:,:,:) ) ! FeL2 |
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| 405 | CALL iom_put("FeP" , zFeP (:,:,:) * tmask(:,:,:) ) ! FeP |
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| 406 | CALL iom_put("TL2" , zTL2 (:,:,:) * tmask(:,:,:) ) ! TL2 |
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| 407 | ENDIF |
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| [3443] | 408 | ENDIF |
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| 409 | ENDIF |
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| 410 | |
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| 411 | IF(ln_ctl) THEN ! print mean trends (used for debugging) |
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| [3449] | 412 | WRITE(charout, FMT="('fechem')") |
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| [3443] | 413 | CALL prt_ctl_trc_info(charout) |
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| 414 | CALL prt_ctl_trc(tab4d=tra, mask=tmask, clinfo=ctrcnm) |
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| 415 | ENDIF |
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| 416 | ! |
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| [7180] | 417 | CALL wrk_dealloc( jpi, jpj, jpk, zFe3, zFeL1, zTL1, ztotlig, precip ) |
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| [7617] | 418 | CALL wrk_dealloc( jpi, jpj, jpk, zscav3d, zcoll3d ) |
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| 419 | #if defined key_ligand |
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| 420 | CALL wrk_dealloc( jpi, jpj, jpk, zlcoll3d ) |
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| 421 | #endif |
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| 422 | |
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| [7180] | 423 | IF( ln_fechem ) THEN |
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| 424 | CALL wrk_dealloc( jpi, jpj, zstrn, zstrn2 ) |
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| 425 | CALL wrk_dealloc( jpi, jpj, jpk, zFe2, zFeL2, zTL2, zFeP ) |
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| 426 | ENDIF |
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| [3443] | 427 | ! |
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| 428 | IF( nn_timing == 1 ) CALL timing_stop('p4z_fechem') |
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| 429 | ! |
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| 430 | END SUBROUTINE p4z_fechem |
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| 431 | |
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| 432 | |
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| 433 | SUBROUTINE p4z_fechem_init |
|---|
| 434 | !!---------------------------------------------------------------------- |
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| 435 | !! *** ROUTINE p4z_fechem_init *** |
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| 436 | !! |
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| 437 | !! ** Purpose : Initialization of iron chemistry parameters |
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| 438 | !! |
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| 439 | !! ** Method : Read the nampisfer namelist and check the parameters |
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| 440 | !! called at the first timestep |
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| 441 | !! |
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| 442 | !! ** input : Namelist nampisfer |
|---|
| 443 | !! |
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| 444 | !!---------------------------------------------------------------------- |
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| [6453] | 445 | NAMELIST/nampisfer/ ln_fechem, ln_ligvar, ln_fecolloid, xlam1, xlamdust, ligand, kfep |
|---|
| [4147] | 446 | INTEGER :: ios ! Local integer output status for namelist read |
|---|
| [3443] | 447 | |
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| [4147] | 448 | REWIND( numnatp_ref ) ! Namelist nampisfer in reference namelist : Pisces iron chemistry |
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| 449 | READ ( numnatp_ref, nampisfer, IOSTAT = ios, ERR = 901) |
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| 450 | 901 IF( ios /= 0 ) CALL ctl_nam ( ios , 'nampisfer in reference namelist', lwp ) |
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| [3443] | 451 | |
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| [4147] | 452 | REWIND( numnatp_cfg ) ! Namelist nampisfer in configuration namelist : Pisces iron chemistry |
|---|
| 453 | READ ( numnatp_cfg, nampisfer, IOSTAT = ios, ERR = 902 ) |
|---|
| 454 | 902 IF( ios /= 0 ) CALL ctl_nam ( ios , 'nampisfer in configuration namelist', lwp ) |
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| [4624] | 455 | IF(lwm) WRITE ( numonp, nampisfer ) |
|---|
| [4147] | 456 | |
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| [3443] | 457 | IF(lwp) THEN ! control print |
|---|
| 458 | WRITE(numout,*) ' ' |
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| 459 | WRITE(numout,*) ' Namelist parameters for Iron chemistry, nampisfer' |
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| 460 | WRITE(numout,*) ' ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~' |
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| [6453] | 461 | WRITE(numout,*) ' enable complex iron chemistry scheme ln_fechem =', ln_fechem |
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| 462 | WRITE(numout,*) ' variable concentration of ligand ln_ligvar =', ln_ligvar |
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| 463 | WRITE(numout,*) ' Variable colloidal fraction of Fe3+ ln_fecolloid =', ln_fecolloid |
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| 464 | WRITE(numout,*) ' scavenging rate of Iron xlam1 =', xlam1 |
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| 465 | WRITE(numout,*) ' scavenging rate of Iron by dust xlamdust =', xlamdust |
|---|
| 466 | WRITE(numout,*) ' ligand concentration in the ocean ligand =', ligand |
|---|
| 467 | WRITE(numout,*) ' rate constant for nanoparticle formation kfep =', kfep |
|---|
| [3443] | 468 | ENDIF |
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| 469 | ! |
|---|
| 470 | IF( ln_fechem ) THEN |
|---|
| 471 | ! initialization of some constants used by the complexe chemistry scheme |
|---|
| 472 | ! ---------------------------------------------------------------------- |
|---|
| [3446] | 473 | spd = 3600. * 24. |
|---|
| [3443] | 474 | con = 1.E9 |
|---|
| 475 | ! LIGAND KINETICS (values from Witter et al. 2000) |
|---|
| [3461] | 476 | ! Weak (L2) ligands |
|---|
| 477 | ! Phaeophytin |
|---|
| 478 | kl2 = 12.2E5 * spd / con |
|---|
| 479 | kb2 = 12.3E-6 * spd |
|---|
| 480 | ! Strong (L1) ligands |
|---|
| 481 | ! Saccharides |
|---|
| 482 | ! kl1 = 12.2E5 * spd / con |
|---|
| 483 | ! kb1 = 12.3E-6 * spd |
|---|
| 484 | ! DFOB- |
|---|
| 485 | kl1 = 19.6e5 * spd / con |
|---|
| 486 | kb1 = 1.5e-6 * spd |
|---|
| [3443] | 487 | ! pcp and remin of Fe3p |
|---|
| 488 | ks = 0.075 |
|---|
| 489 | kpr = 0.05 |
|---|
| [3446] | 490 | ! thermal reduction of Fe3 |
|---|
| 491 | kth = 0.0048 * 24. |
|---|
| [3461] | 492 | ! |
|---|
| [3443] | 493 | ENDIF |
|---|
| 494 | ! |
|---|
| 495 | END SUBROUTINE p4z_fechem_init |
|---|
| 496 | |
|---|
| 497 | #else |
|---|
| 498 | !!====================================================================== |
|---|
| 499 | !! Dummy module : No PISCES bio-model |
|---|
| 500 | !!====================================================================== |
|---|
| 501 | CONTAINS |
|---|
| 502 | SUBROUTINE p4z_fechem ! Empty routine |
|---|
| 503 | END SUBROUTINE p4z_fechem |
|---|
| 504 | #endif |
|---|
| 505 | |
|---|
| 506 | !!====================================================================== |
|---|
| 507 | END MODULE p4zfechem |
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